Read the statement and choose the option correctly.
Correct answer: A. Option A
- A. Option A
- B. Option B
- C. Option C
- D. Option D
Explanation
The general form of a rate law is: Rate =k[A]x[B]y1. Find the effect of changing [A] (Order with respect to A):Compare Experiment 1 and Experiment 2.In Experiment 1: [A]=0.1, [B]=0.1, Rate =2×10−5In Experiment 2: [A]=0.2, [B]=0.1, Rate =4×10−5Notice that [B] stays the same (0.1).When [A] doubles (from 0.1 to 0.2), the Rate also doubles (from 2×10−5 to 4×10−5).If doubling the concentration doubles the rate, the reaction is first order with respect to A. So, x=1.2. Find the effect of changing [B] (Order with respect to B):Compare Experiment 1 and Experiment 3.In Experiment 1: [A]=0.1, [B]=0.1, Rate =2×10−5In Experiment 3: [A]=0.1, [B]=0.2, Rate =4×10−5Notice that [A] stays the same (0.1).When [B] doubles (from 0.1 to 0.2), the Rate also doubles (from 2×10−5 to 4×10−5).If doubling the concentration doubles the rate, the reaction is first order with respect to B. So, y=1.3. Combine to find the Rate Law: Since x=1 and y=1, the rate law is: Rate =k[A]1[B]1 Which simplifies to: Rate =k[A][B]
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About Carboxylic Acids
Carboxylic acids are named and studied through the combined effects of the carbonyl and hydroxyl groups, their preparation, acidity and hydrogen bonding. Reactions include neutralisation, esterification, reduction and conversion into acid chlorides, anhydrides, esters and amides, with emphasis on how these derivatives interconvert.
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