Primary, secondary and tertiary alcohols can be identified and distinguished by:

Correct answer: A. Lucas test

  • A. Lucas test
  • B. Iodoform test
  • C. Baeyer's test
  • D. Silver mirror test

Explanation

The Lucas test differentiates between primary, secondary, and tertiary alcohols. It works because secondary carbocations are more stable and form faster than primary carbocations, and tertiary carbocations are so stable that the reaction takes place almost immediately

This question appeared on the UHS MDCAT 2014 paper, which you can sit online with every answer explained.

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About Alcohols

Alcohols contain a hydroxyl group attached to a saturated carbon atom and are classified as primary, secondary or tertiary. Their nomenclature, hydrogen bonding, acidity, oxidation, dehydration, reaction with sodium and conversion to haloalkanes are covered, along with the distinction between alcohols and phenols, where the hydroxyl group is attached directly to an aromatic ring.

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