Moderate

Maleic acid is stronger than fumaric acid because :

Correct answer: D. Maleic acid shows chelation or intramolecular H-bonding

  • A. Fumaric acid shows intermolecular H-bonding
  • B. Fumaric acid shows intramolecular H-bonding
  • C. Maleic acid is dibasic acid
  • D. Maleic acid shows chelation or intramolecular H-bonding

Explanation

Maleic acid shows intramolecular H-bonding (chelation) and thus-COOH is stabilized. Maleic acid, being a cis-isomer is capable of forming intra-hydrogen bond after losing H+ ion, making the conjugate base much stable than the trans form (fumaric acid) because both the oxygen atoms have strong interaction with the remaining H-atom.

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