During stoichiometric calculations, which of the following laws must be followed?

Correct answer: C. Law of conservation of mass

  • A. Dalton's law
  • B. Avogadro's law
  • C. Law of conservation of mass
  • D. Law of conservation of energy

Explanation

Option A describes the law of partial pressures, which states that the total pressure by a mix of gases is equal to the sum of partial pressures of each of the constituent gases.Option B describes the law which states that equal volumes of gases, at the same temperature and pressure, contain equal numbers of molecules. (NOTE: Do not confuse this with Avogadro's number and the concept of a mole).Option C describes the law which states that matter can neither be created nor destroyed so, the mass of every element, present in the products of a chemical reaction, must be equal to the mass of each and every element present in the reaction, on the reactant side. This is the basis of balancing a chemical equation, without which stoichiometric calculations cannot be carried out so, it is the correct answer.Option D describes the law which states that energy can neither be created nor destroyed; it can only be transferred from one form to the other. This has more relevance in energy conversion and work or power calculations rather than stoichiometry.

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Mole calculations connect mass, number of particles and Avogadro's number, while balanced equations provide the mole ratios used in stoichiometry. Questions cover limiting and excess reactants, theoretical yield and percentage yield, including identifying which reactant is consumed first and comparing the actual product with the maximum possible product.

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