Moderate

During nitration of benzene, the active nitrating agent is:

Correct answer: B. NO+2

  • A. NO3
  • B. NO+2
  • C. NO2
  • D. HNO3

Explanation

Nitration of benzene: Nitric acid and sulfuric acid used in nitration generate nitronium NO2+ ions as electrophiles. Nitronium NO2+ is the nitrating agent.

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About Benzene and Aromatic Compounds

Benzene has a planar ring of delocalised π electrons, giving aromatic stability and equal carbon-carbon bond lengths. The topic covers resonance, electrophilic substitution reactions such as nitration, halogenation, sulphonation and Friedel-Crafts reactions, along with substituent effects and the distinction between substitution in benzene and addition in ordinary alkenes.

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