Benzene is described as aromatic because it

Correct answer: D. is planar, cyclic and has a delocalised system of six pi electrons obeying Huckel's rule

  • A. has a pleasant smell
  • B. contains only carbon and hydrogen
  • C. reacts readily by addition
  • D. is planar, cyclic and has a delocalised system of six pi electrons obeying Huckel's rule

Explanation

Aromaticity in the modern sense requires a planar cyclic conjugated system containing 4n plus 2 pi electrons, which for benzene means six, and this confers exceptional stability. The word originally referred to the smell of such compounds, which is why the first option is the historical but chemically wrong answer. Aromatic compounds characteristically undergo substitution rather than addition.

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About Benzene and Aromatic Compounds

Benzene has a planar ring of delocalised π electrons, giving aromatic stability and equal carbon-carbon bond lengths. The topic covers resonance, electrophilic substitution reactions such as nitration, halogenation, sulphonation and Friedel-Crafts reactions, along with substituent effects and the distinction between substitution in benzene and addition in ordinary alkenes.

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