Aqueous solution of borax above 62°C gives crystals of________________?

Correct answer: B. Na2B4O7.5H2O

  • A. Na2B4O7.4H2O
  • B. Na2B4O7.5H2O
  • C. Na2B4O7.2H2O
  • D. Na2B4O7.10H2O

Explanation

Borax normally crystallizes as Na2B4O7.10H2O, but above about 62°C the decahydrate loses water and forms the pentahydrate, Na2B4O7.5H2O. The likely wrong choice is d, because students remember the common decahydrate formula without considering the effect of temperature.

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