A rise of 10 degrees Celsius roughly doubles the rate of many reactions mainly because

Correct answer: D. a much larger fraction of molecules acquire energy equal to or above the activation energy

  • A. the activation energy of the reaction falls
  • B. the concentration of the reactants increases
  • C. the molecules become larger
  • D. a much larger fraction of molecules acquire energy equal to or above the activation energy

Explanation

The Maxwell Boltzmann distribution shifts to the right on heating, and because the activation energy lies out in the tail of the curve, even a small temperature rise multiplies the number of molecules beyond it. The increase in collision frequency is real but accounts for only a few per cent of the effect. Activation energy itself is a property of the reaction and is not changed by heating.

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About Factors Affecting Rate of Reaction

Reaction rate depends on the nature and concentration of reactants, pressure for gases, temperature, surface area and catalysts. Collision theory explains these effects through collision frequency, orientation and activation energy, while questions often distinguish a catalyst's effect on reaction rate from its lack of effect on equilibrium composition.

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