Why is the oxidation of ketones not easy?
Correct answer: B. Because it involves breaking of C-C bond
- A. Because it involves breaking of C-O bond
- B. Because it involves breaking of C-C bond
- C. Because it involves breaking of C-H bond
- D. Because it involves breaking of C=C bond
Explanation
Option A: Because it involves breaking of C-O bond: This option is not correct. The oxidation of ketones does not involve breaking of the carbon-oxygen (C-O) bond. In fact, the carbonyl group (C=O) remains intact during oxidation. Option B: Ketones contain a carbonyl group (C=O), where the carbon atom is double bonded to an oxygen atom. In oxidation reactions, the ketone molecule undergoes a transfer of electrons, resulting in the increase of the oxidation state of the carbon atom. This typically requires breaking the carbon-carbon bond adjacent to the carbonyl group. Option C: Because it involves breaking of C-H bond: This option is not correct. Ketone oxidation generally does not involve breaking of carbon-hydrogen (C-H) bonds. The focus is primarily on modifying the carbonyl group. Option D: Because it involves breaking of C=C bond: This option is not correct. Ketones do not have a carbon-carbon double bond (C=C). Instead, they have a carbon-oxygen double bond (C=O) in the form of the carbonyl group.
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About Aldehydes and Ketones
Aldehydes and ketones contain the polar carbonyl group, but aldehydes are generally more readily oxidised and more reactive than ketones. Coverage includes preparation by oxidation or reduction routes, nucleophilic addition of reagents such as hydrogen cyanide and bisulfite, and tests that distinguish aldehydes from ketones.
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