Which reagent distinguishes ethanol from phenol?

Correct answer: B. Bromine water

  • A. Sodium metal
  • B. Bromine water
  • C. Water
  • D. A lighted splint

Explanation

Phenol decolourises bromine water immediately and gives a white precipitate of the tribromo compound, whereas ethanol produces no visible change. Sodium metal is not suitable, since both compounds contain a hydroxyl group and both release hydrogen with it. Neutral iron three chloride is the other reliable distinguishing test.

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About Phenols

Phenols contain a hydroxyl group directly bonded to an aromatic ring, making them more acidic than alcohols because the phenoxide ion is resonance-stabilised. Reactions include ionisation with bases, electrophilic substitution, bromination, nitration and oxidation, with attention to the difference between phenols and aliphatic alcohols.

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