Which of the following transition metals has the highest variable oxidation state?

Correct answer: D. Mn

  • A. W
  • B. Pt
  • C. Hg
  • D. Mn

Explanation

The transition metals have variable oxidation states due to the presence of unpaired electrons in their d orbitals. The highest oxidation state is determined by the number of electrons that can be accommodated in the d orbitals. The maximum number of unpaired electrons is five, which corresponds to a +7 oxidation state. Manganese has five unpaired electrons in its d orbitals, which allows it to have a maximum oxidation state of +7, the highest among the transition metals.

This question appeared on the NUMS 2019 (cancelled sitting) paper, which you can sit online with every answer explained.

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About Electronic Structure of d-Block Elements

The electronic structure of d-block elements covers the filling of the (n-1)d and ns orbitals, general electronic configurations, and the exceptions shown by chromium and copper. It explains how partially filled d orbitals produce variable oxidation states, coloured ions, magnetic behaviour and complex formation, while distinguishing transition elements from elements with completely filled d subshells.

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