Which of the following solvents is used for the extraction of H3PO4 from CaCl2 solution during manufacture of ortho-phosphoric acid by wet process employing hydrochloric acid leaching ?

Correct answer: B. Butyl alcohol

  • A. Isopropyl alcohol
  • B. Butyl alcohol
  • C. Toluene
  • D. Hexane

Explanation

n-Butyl alcohol selectively extracts phosphoric acid from the hydrochloric-acid leach liquor, while calcium chloride remains mainly in the aqueous phase. This separation is a liquid-liquid solvent-extraction step.

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