Which of the following is the Clausius-Clapeyron Equation ?

Correct answer: C. loge (p/p0) = (λ/R) (1/T0 - 1/T)

  • A. PV = RT + B/V + y/V2 + ....
  • B. (P + a/V2)(V-b) = RT
  • C. loge (p/p0) = (λ/R) (1/T0 - 1/T)
  • D. p = [RT/(V - b)] - (a/TV2)

Explanation

The integrated Clausius-Clapeyron equation relates vapour pressures at two temperatures through latent heat, giving ln(p/p0) = (λ/R)(1/T0 − 1/T) when λ is treated as constant. The other expressions are virial or van der Waals-type equations of state.

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