Asked in FBISE Chemistry 2022 — Paper 2 2022Moderate

Which of the following gases will be most non-ideal at - 10 deg * C ?

Correct answer: D. SO2

  • A. C*O_{2}
  • B. N_{2}
  • C. H_{2}
  • D. SO2

Explanation

Presence of electrons is large in sulphur dioxide and hence greater van der waals interactions . Due to greater intermolecular force it has high boiling point and requires high temperature to behave as ideally. Hence sulphur dioxide behave as least ideal gas at low temperature.

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About Real and Ideal Gases

An ideal gas is modelled as particles with negligible volume and no intermolecular attraction, obeying Boyle's, Charles's and Avogadro's laws through PV = nRT. Real gases deviate from this behaviour, especially at high pressure and low temperature, because particle volume and attractive forces matter; the van der Waals equation explains these corrections.

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