Asked in MDCAT Free Mock 2024 2024Moderate

Which of the following compounds is not reduced by NaBH4?

Correct answer: D. Alkene

  • A. Acetaldehyde
  • B. Acetone
  • C. Aldehydes
  • D. Alkene

Explanation

NaBH4 cannot reduce alkenes into alkanes because in a C=C there is no nucleophilic nature, the H- ion needs a positive carbon to attack, like in a functional group with oxygen the carbon has a slight possitive charge.

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About Reactivity of Aldehydes and Ketones

The polar carbonyl group makes aldehydes and ketones undergo nucleophilic addition, reduction and condensation reactions. Aldehydes are generally more reactive and oxidise readily to carboxylic acids, whereas ketones resist mild oxidation; reactions with hydrogen cyanide, sodium bisulfite and 2,4-DNP help identify their behaviour.

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679 free Aldehydes and Ketones MCQs from Chemistry, each with the correct answer and an explanation. Unlimited attempts, no account needed.

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