What happens when H+ is added to ammonium hydroxide and ammonium chloride buffer?

Correct answer: C. Reaction will move forward

  • A. More ammonium hydroxide is formed
  • B. Reaction will move reverse
  • C. Reaction will move forward
  • D. No effect on equilibrium

Explanation

The added hydrogen ions are mopped up by the weak base ammonium hydroxide, which reacts forward to give ammonium ions and water, so the pH barely shifts. This is exactly what buffering means: the reservoir of base neutralises added acid. If alkali were added instead, the ammonium ions from the salt would supply protons to neutralise it.

This question appeared on the UHS MDCAT 2025 paper, which you can sit online with every answer explained.

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About Buffer Solutions

Buffer solutions resist changes in pH when small amounts of acid or base are added, using a weak acid and its conjugate base or a weak base and its conjugate acid. Work includes buffer action, the common-ion effect, Henderson-Hasselbalch calculations, buffer capacity, and the difference between acidic and basic buffers.

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