The vapour pressure of a liquid is the pressure exerted by its vapour when

  • A. the liquid has completely evaporated
  • B. the vapour is in dynamic equilibrium with the liquid in a closed container
  • C. the liquid is boiling in an open vessel
  • D. the container is completely empty of air

Explanation

In a closed vessel evaporation and condensation eventually occur at the same rate, and the constant pressure of vapour at that point is the equilibrium vapour pressure of the liquid at that temperature. It depends only on the liquid and the temperature, never on the volume of the container or the amount of liquid present. In an open vessel equilibrium is never reached because vapour escapes.

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