Moderate

The solubility product of CdS is 9.0×10−4 mol². dm−6. The maximum concentration of Cd+2 ions is

Correct answer: C. 3×10−2 mole. dm−3

  • A. 1.41×10−5mol.dm−3
  • B. 2×10−3 mol. dm−3
  • C. 3×10−2 mole. dm−3
  • D. 3×10−3 mol. dm−3

Explanation

3×10−2 mole. dm−3: Understanding Solubility Product (Ksp):CdS is a sparingly soluble salt. When it dissolves, it dissociates into Cd²⁺ and S²⁻ ions: CdS(s) ⇌ Cd²⁺(aq) + S²⁻(aq).The Ksp is defined as [Cd²⁺][S²⁻].Since CdS dissociates in a 1:1 ratio, [Cd²⁺] = [S²⁻]. Let's call this concentration 's' (solubility).Therefore, Ksp = s².Calculations:We are given Ksp = 9.0 × 10⁻⁴.s² = 9.0 × 10⁻⁴s = √(9.0 × 10⁻⁴) s = 3.0 × 10⁻² mol.dm⁻³

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About Chemical Equilibrium

Reversible reactions reach dynamic equilibrium when forward and reverse rates become equal, and Le Chatelier's principle predicts the effect of changing concentration, pressure or temperature. The chapter also covers solubility product, the common ion effect, buffer action and the conditions used in Haber's process, with equilibrium shifts distinguished from changes in the equilibrium constant.

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