Asked in PMC Practice Test 32 (2021) 2021

The order of reaction for which half-life is inversly proportional to the concentration of reactant is:

Correct answer: A. Second order

  • A. Second order
  • B. Zero order
  • C. First order
  • D. Third order

Explanation

In a second-order reaction, the relationship between half-life and concentration is such that the half-life is inversely proportional to the concentration of the reactant raised to the power of one. As the concentration decreases due to the reaction progressing, the half-life increases proportionally. Therefore, higher concentrations result in shorter half-lives, demonstrating an inverse relationship between concentration and half-life.

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About Order of Reaction

Reaction order shows how the rate depends on the concentration of each reactant, as expressed in the rate law. Coverage includes zero, first and second-order reactions, integrated rate equations, half-life, units of rate constants and the distinction between overall order and molecularity.

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