Moderate

The only o, p−directing group which is deactivating in nature is:

Correct answer: C. -X (halogens)

  • A. -NH2
  • B. -OH
  • C. -X (halogens)
  • D. -R (alkyl groups)

Explanation

Halides are ortho-para- directing groups but unlike most ortho-para- directors halides tend to deactivate benzene. This unusual behaviour can be explained by two properties:1. Since the halogens are very electronegative they cause inductive withdrawal (withdrawal of electrons from the carbon atom of benzene).2. Since the halogens have non-bonding electrons they can donate electron density through pi bonding (resonance donation).Option C is correct.

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About Alkyl Halides

Alkyl halides are named and related to their carbon-halogen structure, polarity and reactivity. The key reactions are nucleophilic substitution by SN1 and SN2 mechanisms and elimination by E1 and E2 mechanisms, including how substrate structure, nucleophile, base, solvent and temperature influence substitution versus elimination.

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