Moderate

The number of Cl- ions per unit cell of a simple cubic lattice at the corner is/are:

Correct answer: A. 1

  • A. 1
  • B. 3
  • C. 4
  • D. 6

Explanation

- In a simple cubic lattice, each corner is shared by eight adjacent unit cells.- Each corner atom/ion contributes (1/8) to the unit cell it is a part of.- For Cl- ions in a simple cubic lattice, considering their distribution, each Cl- ion is shared equally among eight neighboring unit cells. Hence, only (1/8) of a Cl- ion is present per unit cell at each corner.- Since each corner contributes (1/8) of a Cl- ion and there is one corner in a unit cell, the total contribution of Cl- ions from corners to a single unit cell is (1 times 1/8 = 1/8), which is approximately 1. Therefore, option a is correct.

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About Shape of Ionic Crystals

Ionic crystal shape depends on the regular arrangement of oppositely charged ions in a three-dimensional lattice. The topic covers coordination number, radius ratios, lattice geometry and structures such as sodium chloride, caesium chloride and zinc sulfide, which should not be confused with the molecular shapes predicted by VSEPR theory.

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