The non-ideal behaviour results chiefly from________________?

Correct answer: C. Intermolecular attractions and finite volume

  • A. Intermolecular attraction and infinite volume
  • B. Elastic collisions and finite volume
  • C. Intermolecular attractions and finite volume
  • D. Intermolecular attraction only

Explanation

Real gases deviate from ideal behaviour because their molecules attract one another and occupy finite volume. The ideal-gas model assumes no intermolecular attractions and negligible molecular volume. The likely wrong choice is d, which ignores the effect of finite molecular volume at high pressure.

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About Real and Ideal Gases

An ideal gas is modelled as particles with negligible volume and no intermolecular attraction, obeying Boyle's, Charles's and Avogadro's laws through PV = nRT. Real gases deviate from this behaviour, especially at high pressure and low temperature, because particle volume and attractive forces matter; the van der Waals equation explains these corrections.

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