Moderate

The equation, (d loge PA/d loge xA) = (d loge PA/d loge xB) applicable to a binary solution of components. A and B in equilibrium with their vapors at constant temperature and pressure is called the _____________ equation?

Correct answer: D. Gibbs-Duhem-Margules

  • A. Van Laar
  • B. Margules
  • C. Gibbs-Duhem
  • D. Gibbs-Duhem-Margules

Explanation

For a binary vapour-liquid system at constant temperature and pressure, the relation between the logarithmic changes in partial pressures and liquid compositions is the Gibbs-Duhem-Margules equation. Van Laar and Margules are activity-coefficient models, not the name of this general thermodynamic relation.

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