S(s) + 3/2 O2(g) ➞ SO3(g) + 2x KJ SO2(g) + 1/2 O2(g) ➞ SO3(g) + y kJFind the heat of formation of SO2(g) .
Correct answer: C. (2x -y)
- A. (y - 2x)
- B. (x + y)
- C. (2x -y)
- D. 2x/y
Explanation
Reverse the second reaction and change the sign of its enthalpy change: SO3(g) + y kJ → SO2(g) + 1/2 O2(g) Multiply the first reaction by 2 to match the stoichiometry of the oxygen molecules in the reversed second reaction: 2(S(s) + 3/2 O2(g) → SO3(g) + 2x kJ) Add the two reactions together to get the desired reaction: 2(S(s) + 3/2 O2(g) → SO3(g) + 2x kJ) + (SO3(g) + y kJ → SO2(g) + 1/2 O2(g)) The intermediate terms cancel out: 2S(s) + 3O2(g) → 2SO3(g) + 2x kJ + y kJ Simplify the equation: 2S(s) + 3O2(g) → 2SO3(g) + (2x + y) kJ Now, we can isolate the desired reaction and the heat of formation of SO2(g): 2SO3(g) → 2S(s) + 3O2(g) + (2x + y)kJ The heat of the formation of SO2(g) from its elements in their standard states is equal to the value of (2x + y) kJ, hence option C is correct.
Report an error
The more specific you are, the faster it gets fixed. A source beats an opinion.
Prefer email? [email protected]
About Thermochemistry and Energetics of Chemical Reactions
Thermochemistry measures energy changes in chemical reactions and distinguishes exothermic from endothermic processes. Work covers systems, surroundings and state functions, internal energy, the first law of thermodynamics, enthalpy and Hess's law, including the sign conventions used when heat enters or leaves a system.
Practise Thermochemistry and Energetics of Chemical Reactions
728 free Thermochemistry and Energetics of Chemical Reactions MCQs from Chemistry, each with the correct answer and an explanation. Unlimited attempts, no account needed.
Discussion
Stuck on an option, or know a faster way to get there? Ask or explain it here.
No comments yet. Be the first to explain this one.
Exams that ask Chemistry questions like this
Chemistry is on 14 papers prepared for on TestUstad, and all of them draw the same bank, so this question is worth knowing for every one of them.
More Thermochemistry and Energetics of Chemical Reactions questions
Among the following, for which reaction, heat of reaction represents bond energy of all:
The heat change in a reaction does not depend upon which of the following:
According to the equation C6H6(I) + 15/2 O2(g) ➞ 6CO2(g) + 3H2O(1), H = -3264.4 KJ/mol, the energy evolved when 7.8 g of lizene is burnt in air will be:
Plants and living beings are examples of:
The work done by a system is 10 Joule, when 40 Joule heat is supplied to it. What is the increase in internal energy of system?
The energy of the system during endothermic reactions is: