Asked in ETEA MDCAT 2014 2014Moderate

Reduction of acetaldehyde with H2/Ni gives:

Correct answer: A. Ethanol

  • A. Ethanol
  • B. Ethanoic acid
  • C. Ethane
  • D. Ethylene

Explanation

H2/Ni are strong reducing agents which reduces aldehydes to primary alcohols and ketones to secondary alcohols.

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About Reactivity of Aldehydes and Ketones

The polar carbonyl group makes aldehydes and ketones undergo nucleophilic addition, reduction and condensation reactions. Aldehydes are generally more reactive and oxidise readily to carboxylic acids, whereas ketones resist mild oxidation; reactions with hydrogen cyanide, sodium bisulfite and 2,4-DNP help identify their behaviour.

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