Pick out the wrong statement. A. The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction________________?

Correct answer: B. With increase in temperature, the equilibrium constant increases for an exothermic reaction

  • A. The equilibrium constant of a reaction depends upon temperature only
  • B. With increase in temperature, the equilibrium constant increases for an exothermic reaction
  • C. The conversion for a gas phase reaction increases with increase in pressure, if there is a
  • D. decrease in volume accompanying the reaction

Explanation

For an exothermic reaction, heat behaves like a product, so increasing temperature shifts equilibrium backward and decreases the equilibrium constant. The pressure statements are consistent with Le Chatelier's principle when the volume change is specified.

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