Pick out the system with minimum boiling azeotrope at 1 atm ?

Correct answer: C. Ethyl alcohol-water

  • A. Benzene-toluene
  • B. Hydrochloric acid-water
  • C. Ethyl alcohol-water
  • D. All A., B. and C.

Explanation

Ethanol and water form a minimum-boiling azeotrope at approximately atmospheric pressure because their vapour-liquid equilibrium shows positive deviation from Raoult's law. Benzene-toluene is nearly ideal, while hydrochloric acid-water forms a maximum-boiling azeotrope.

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