Asked in PMC Practice Test 22 (2021) 2021Moderate

Iodine has greater heat of sublimation then its family members due to presence of stronger _.

Correct answer: B. London dispersion forces

  • A. H-bonding
  • B. London dispersion forces
  • C. Dipole-dipole force
  • D. Chemical bonding

Explanation

B is correct option because Iodine sublimes rather than melting and boiling. Its molecules prefer to stay in the gaseous state as they are not held together by strong intermolecular forces in their solid-state. Iodine has greater number of electrons about 53 electrons around its nucleus.So unsymmetrical electronic distribution or polarizibility of iodine is also very high.Due to this Strong London forces of dispersion are present among iodine molecules.That's why heat of sublimation of iodine is very high

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About Properties of Liquids

Liquid behavior depends on intermolecular forces, which produce surface tension, viscosity, capillary action and a definite volume without a fixed shape. The topic also covers vapor pressure, evaporation, boiling point and the effect of temperature and external pressure, while distinguishing evaporation at the surface from boiling throughout the liquid.

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