Increasing the pressure has NO effect on the position of the equilibrium H2 + I2 gives 2HI because

  • A. the reaction is exothermic
  • B. hydrogen iodide is a gas
  • C. the number of moles of gas is the same on both sides
  • D. the reaction has no catalyst

Explanation

Pressure changes shift an equilibrium only when the two sides differ in the number of gas molecules, and here there are two moles on each side, so neither direction relieves the stress. The rate of reaching equilibrium does rise with pressure, but the position stays put. Temperature changes will still shift this equilibrium, since the two directions differ in enthalpy.

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