In a bomb calorimeter, the heat of reaction measured corresponds to the change in

Correct answer: B. internal energy, since the volume is constant

  • A. enthalpy, since the pressure is constant
  • B. internal energy, since the volume is constant
  • C. entropy
  • D. free energy

Explanation

A bomb calorimeter is a sealed rigid vessel, so the volume cannot change, no expansion work is done and all the energy released appears as heat, which equals the change in internal energy. A reaction in an open vessel is at constant pressure and gives the enthalpy change instead. The two differ only by the work done pushing back the atmosphere.

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About Internal Energy

Internal energy is the total microscopic kinetic and potential energy of a system and is a state function. The first law, ΔU = q + w, connects changes in internal energy with heat and work, including sign conventions, expansion or compression and constant-volume processes.

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