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If a1 and a2 are the relative volatilities when the pressure in the distillation column is 1 and 2 atm respectively. Pick out the correct statement ?

Correct answer: D. None of these

  • A. a1 = a2
  • B. a1 = 2a2
  • C. a1 = 0.5 a2
  • D. None of these

Explanation

Relative volatility depends on the vapour-liquid equilibrium and generally changes with pressure and temperature, but its change between 1 and 2 atm is not fixed by a simple ratio. Therefore, none of the stated equalities can be guaranteed.

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