Heterolytic fission of a covalent bond produces

Correct answer: C. a positive and a negative ion, because both electrons go to one atom

  • A. two free radicals
  • B. two neutral atoms
  • C. a positive and a negative ion, because both electrons go to one atom
  • D. no change in the molecule

Explanation

In heterolytic fission the shared pair leaves with the more electronegative atom, giving oppositely charged ions such as a carbocation and a halide, and this is typical of polar solvents and ionic mechanisms. Homolytic fission splits the pair evenly and gives two free radicals, which is what happens under ultraviolet light or high temperature. Recognising which type a reaction uses is the key to predicting its mechanism.

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About Classification of Organic Compounds

Organic compounds are classified by carbon skeleton into open-chain, branched-chain and cyclic compounds, including homocyclic and heterocyclic types. The classification also uses functional groups to distinguish hydrocarbons, halo compounds, alcohols, aldehydes, ketones, carboxylic acids and their derivatives, which is different from naming compounds by IUPAC rules.

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