For the irreversible reaction, Ca+ 2C = Ca C2 , Δ H°298 = - 60000 J . mole-1 . If a system initially containing 2 moles of calcium, 3 moles of carbon and 1 mole of calcium carbide is allowed to react to completion, the heat evolved at 298 K will be__________________?

Correct answer: C. 90,000 J

  • A. 30,000 J
  • B. 60,000 J
  • C. 90,000 J
  • D. 2,40,000 J

Explanation

The reaction extent is limited by calcium: 2 mol Ca allows 2 mol of reaction, while 3 mol carbon allows 1.5 mol, so carbon is limiting. Heat evolved is 1.5 × 60,000 = 90,000 J.

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