For sets of values of quantum numbers (n, l, m and s) are given below. Which of these does not provide a permissible solution of the wave equation?
Correct answer: E. Both B and C
- A. 3, 2, -2, 1/2
- B. 3, 3, 1, -1/2
- C. 0, 3, 1, -1/2
- D. 3, 1, 1, -1/2
- E. Both B and C
Explanation
The correct answer is Option E both B and C : 3, 3, 1, -1/2. According to the rules of quantum numbers, the azimuthal quantum number l must be in the range 0 to n-1. Therefore, l=3 is not permissible when n=3, as l should be less than n.In Option A and D, the values of l and m are within permissible ranges for n=3. In Option C, the principal quantum number n cannot be zero, making it invalid.
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