For a reaction A gives products, doubling the concentration of A leaves the rate unchanged. The reaction is

Correct answer: D. zero order in A

  • A. first order in A
  • B. second order in A
  • C. third order in A
  • D. zero order in A

Explanation

If concentration has no effect on rate then the exponent of that term must be zero, since anything raised to the power zero equals one. Had the rate doubled the reaction would be first order, and had it quadrupled it would be second order, which is the reasoning used to find orders experimentally. Zero order behaviour usually signals a saturated catalyst or enzyme.

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About Order of Reaction

Reaction order shows how the rate depends on the concentration of each reactant, as expressed in the rate law. Coverage includes zero, first and second-order reactions, integrated rate equations, half-life, units of rate constants and the distinction between overall order and molecularity.

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