Enthalpy means

Correct answer: D. Heat content

  • A. Disorder
  • B. Transition state
  • C. Rate constant
  • D. Heat content

Explanation

H = E + PV.Enthalpy is a state function. Also known as heat content.It is measured in joules. It is not possible, to measure the enthalpy of a system in a given state. However, change in enthalpy ( ∆H ) can be measured for a change in the state of system . A change in enthalpy of a system can be written as:∆H = ∆E + ∆(PV) or ∆H = ∆E + V∆P + P∆V.Since, the gas is kept at constant pressure, = 0Hence ∆H = ∆E + P∆V .In case of liquids and solids, the changes in state do not cause signiicant volume change i.e. ∆V = 0. For such process, ∆H and ∆E are approximately the same i.e. ∆H ≈ ∆E.According to irst law of thermodynamics:∆E = q + w.If w is pressure - volume work done by the system, then:w = - P∆V So ∆E = q - P∆V.Putting the value of ∆E in equation (4) we get: ∆H = q - P∆V + P∆V.∆H = q.Since the pressure is constant, therefore,∆H = qp.

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About Thermochemistry and Energetics of Chemical Reactions

Thermochemistry measures energy changes in chemical reactions and distinguishes exothermic from endothermic processes. Work covers systems, surroundings and state functions, internal energy, the first law of thermodynamics, enthalpy and Hess's law, including the sign conventions used when heat enters or leaves a system.

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