By product produced during hydrolysis of alkane nitrile in basic medium is:

Correct answer: A. NH3

  • A. NH3
  • B. (NH4)2 SO4
  • C. NH4CI
  • D. NH4NO3

Explanation

Option A is correct.The by-product produced during the hydrolysis of alkane nitrile in a basic medium is ammonia (NH3). When an alkane nitrile is hydrolyzed in a basic medium, the nitrogen atom is converted to an ammonium ion (NH4+). The ammonium ion is then neutralized by a hydroxide ion (OH-) to form ammonia gas (NH3). Here are the steps of the reaction: The nitrogen atom in the alkane nitrile is attracted to the hydroxide ion (OH-) from the base. The hydroxide ion abstracts a proton from the nitrogen atom. As a result, the nitrogen atom becomes positively charged and is converted to an ammonium ion (NH4+). The ammonium ion (NH4+) is then neutralized by another hydroxide ion (OH-) from the base. The neutralization reaction produces water (H2O) and ammonia gas (NH3). The overall reaction of the hydrolysis of alkane nitrile in a basic medium is: R-CN + H2O → R-COOH + NH3 Where R is an alkyl group.

Written and checked by , M.Phil ChemistryLast updated
Report an error

The more specific you are, the faster it gets fixed. A source beats an opinion.

Prefer email? [email protected]

About Carboxylic Acids

Carboxylic acids are named and studied through the combined effects of the carbonyl and hydroxyl groups, their preparation, acidity and hydrogen bonding. Reactions include neutralisation, esterification, reduction and conversion into acid chlorides, anhydrides, esters and amides, with emphasis on how these derivatives interconvert.

Practise Carboxylic Acids

550 free Carboxylic Acids MCQs from Chemistry, each with the correct answer and an explanation. Unlimited attempts, no account needed.

Discussion

Stuck on an option, or know a faster way to get there? Ask or explain it here.

No comments yet. Be the first to explain this one.

Exams that ask Chemistry questions like this

Chemistry is on 14 papers prepared for on TestUstad, and all of them draw the same bank, so this question is worth knowing for every one of them.

More Carboxylic Acids questions