At 40°C, the ionic product of water, Kw , is:

Correct answer: B. 2.9×10⁻¹⁴

  • A. 1.0×10⁻¹⁴
  • B. 2.9×10⁻¹⁴
  • C. 3.8×10⁻¹⁴
  • D. 1.8×10⁻¹⁴

Explanation

The autoionization of water is an endothermic process. According to Le Chatelier's principle, increasing the temperature will shift the equilibrium to the right, increasing the concentrations of H⁺ and OH⁻. This results in a larger K value at higher temperatures; at 40°C, it is approximately 2.9×10⁻¹⁴.

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