An Azeotropic solution of two liquids has boiling point lower than either of them, when it_____________?

Correct answer: B. Shows positive deviation from Raoult's law

  • A. Is saturated
  • B. Shows positive deviation from Raoult's law
  • C. Shows negative deviation from Raoult's law
  • D. Is unsaturated

Explanation

Positive deviation from Raoult's law raises the total vapour pressure above the ideal value, so the liquid boils at a lower temperature than either pure component. This produces a minimum-boiling azeotrope.

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