Moderate

An alcohol is converted to an aldehyde with same number of carbon atoms as that of alcohol in the presence of K2Cr2O7/H2SO4 the alcohol is:

Correct answer: B. CH3CH2CH2OH

  • A. CH3Cl(CH)2OH
  • B. CH3CH2CH2OH
  • C. (CH3)3COH
  • D. (CH3)3CHOH

Explanation

(B) is a PRIMARY alcohol and would be oxidised to an aldehyde with the same number of carbon atoms.

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About Aldehydes and Ketones

Aldehydes and ketones contain the polar carbonyl group, but aldehydes are generally more readily oxidised and more reactive than ketones. Coverage includes preparation by oxidation or reduction routes, nucleophilic addition of reagents such as hydrogen cyanide and bisulfite, and tests that distinguish aldehydes from ketones.

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