A solid compound dissolves readily in water to give a weakly alkaline solution. On evaporation of the water, X was recovered unchanged. Which one of the following could be X?

Correct answer: C. C6H5 O-Na+

  • A. CH3 NH3 Cl
  • B. CH3 O- Na+
  • C. C6H5 O-Na+
  • D. C6H5NH2
  • E. H2NCH2CO2H

Explanation

The sodium salt of phenol, which is weakly acidic. When dissolved in water, it would give a weakly alkaline solution due to the hydrolysis of the phenoxide ion. On evaporation, we would recover the original compound unchanged.

This question appeared on the NUMS 2016 paper, which you can sit online with every answer explained.

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About Salts and Hydrolysis

Salt hydrolysis explains how ions from weak acids or weak bases react with water and affect the pH of a solution. The content covers acidic, basic and neutral salts, hydrolysis equations, Ka, Kb and Kw relationships, degree of hydrolysis and buffer connections, distinguishing hydrolysis from simple acid-base neutralisation.

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