A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that _____________ in the two reactors?

Correct answer: B. Conversion in both will be the same but concentrations will be different

  • A. Both conversion as well as concentration are same
  • B. Conversion in both will be the same but concentrations will be different
  • C. Both the conversion as well as concentrations will be different
  • D. None of these

Explanation

For a first-order reaction, the mole balance gives dNA/dt = -kNA, so the fractional conversion after a given time is independent of reactor volume. The concentration changes because the variable-volume reactor has a different volume, making option b correct.

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