Asked in ETEA MDCAT 2011 2011Moderate

A buffer solution containing H2CO3 and NaHCO3 is to be prepared to maintain a pH of 7.00. What must be the ratio NaHCO3 in order to realize such a pH if Ka of carbonic HCO3 acid is 4.3 x 10^7?

Correct answer: D. 4.3

  • A. 43
  • B. 48
  • C. 0.43
  • D. 4.3

Explanation

pH=pKa+ Log NaHCO3/H2CO3 7=4.3*10^-7+ Log NaHCO3/H2CO3 Log NaHCO3/H2CO3=7 NaHCO3/H2CO3=10^7 NaHCO3=10^7* H2C03 NaHCO3=10^7*4.3^-7 NaHCO3=4.3

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About Buffer Solutions

Buffer solutions resist changes in pH when small amounts of acid or base are added, using a weak acid and its conjugate base or a weak base and its conjugate acid. Work includes buffer action, the common-ion effect, Henderson-Hasselbalch calculations, buffer capacity, and the difference between acidic and basic buffers.

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