The shape of the boron trifluoride molecule, BF3, is

Correct answer: D. trigonal planar with bond angles of 120 degrees

  • A. pyramidal
  • B. bent
  • C. tetrahedral
  • D. trigonal planar with bond angles of 120 degrees

Explanation

Boron forms three bonds and has no lone pair, so the three electron regions lie flat at 120 degrees, and the molecule is an exception to the octet rule with only six electrons round the central atom. That electron deficiency is why boron trifluoride readily accepts a lone pair and acts as a Lewis acid. Ammonia looks similar on paper but is pyramidal because of its lone pair.

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Valence shell electron pair repulsion theory predicts molecular shape by arranging bonding pairs and lone pairs around a central atom to minimize repulsion. Questions cover linear, trigonal planar, tetrahedral, trigonal bipyramidal and octahedral electron geometries, bond angles and distortions caused by lone pairs. Electron geometry is not always the same as molecular shape.

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