The correct order of reactivity of alkyl halides is.

Correct answer: C. R-I > R-Br > R-Cl > R-F

  • A. R-Br > R-CL > R-F > R-I
  • B. R-Br > R-F > R-I > R-CI
  • C. R-I > R-Br > R-Cl > R-F
  • D. R-Cl > R-I > R-Br > R-F

Explanation

The reactivity of alkyl halides towards nucleophilic substitution reactions follows the order:R-I (alkyl iodide) > R-Br (alkyl bromide) > R-Cl (alkyl chloride) > R-F (alkyl fluoride)This order is based on the strength of the carbon-halogen bond, with the weaker bonds being more reactive. The bond strength decreases from R-F (strongest) to R-I (weakest), making R-I the most reactive and R-F the least reactive

This question appeared on the KMU MDCAT 2023 (retake) paper, which you can sit online with every answer explained.

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About Nomenclature, Structure and Reactivity

Alkyl halides are named by selecting the longest carbon chain and locating the halogen substituent, while their structures are classified as primary, secondary or tertiary. Their reactivity includes nucleophilic substitution and elimination, with the behaviour of leaving groups and the distinction between SN1 and SN2 mechanisms linked to substrate structure.

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458 free Alkyl Halides MCQs from Chemistry, each with the correct answer and an explanation. Unlimited attempts, no account needed.

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