The addition of hydrogen cyanide to ethanal gives

  • A. ethanoic acid
  • B. 2-hydroxypropanenitrile
  • C. ethanol
  • D. propanone

Explanation

The cyanide ion attacks the carbonyl carbon and the resulting alkoxide picks up a proton, giving a hydroxynitrile with one more carbon than the starting aldehyde. The reaction is catalysed by a trace of base, which generates the cyanide nucleophile. The product can be hydrolysed to a hydroxy acid, making this a useful chain lengthening step.

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