The colour of transition metal complexes is due to:
Correct answer: A. d-d transitions of electrons
- A. d-d transitions of electrons
- B. Paramagnetic nature of transition elements
- C. Ionization
- D. Loss of s-electrons
Explanation
The color of transition metal complexes is primarily due to d-d transitions. In these complexes, the presence of a partially filled d subshell allows electrons to transition between different d orbitals. When light is absorbed, electrons are promoted to higher energy levels, and the specific wavelengths absorbed correspond to the color observed. This is why transition metals with no unpaired d electrons, such as Sc+3, Ti+4, V+5, Cu+1, and Zn+2, do not display the characteristic d-d transitions and are often colorless.Option B is incorrect because the paramagnetic nature of transition metals is related to unpaired electrons affecting magnetic properties rather than color. Option C is incorrect because ionization involves electron removal, not affecting the color directly. Option D is incorrect as the loss of s-electrons pertains to oxidation states rather than the origin of color in complexes.
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About Electronic Structure of d-Block Elements
The electronic structure of d-block elements covers the filling of the (n-1)d and ns orbitals, general electronic configurations, and the exceptions shown by chromium and copper. It explains how partially filled d orbitals produce variable oxidation states, coloured ions, magnetic behaviour and complex formation, while distinguishing transition elements from elements with completely filled d subshells.
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