Moderate

For a reaction 2 NH3 ➞ N2,+ 3H2, which of the following statements is correct.

Correct answer: C. ∆H = ∆E

  • A. ∆H = 0
  • B. ∆H > ∆E
  • C. ∆H = ∆E
  • D. ∆H < ∆E

Explanation

For the reaction 2 NH3 ➞ N2 + 3 H2, the correct statement is that ∆H = ∆E. This is because, in many reactions at constant pressure, the change in enthalpy (∆H) and the change in internal energy (∆E) can be equal, particularly when there is no significant pressure-volume work involved. In this decomposition reaction, the work done on or by the system is minimal, leading to ∆H equaling ∆E. Other options are incorrect because they either misrepresent the relationship between ∆H and ∆E or wrongly assume ∆H as zero, which is not characteristic of an exothermic reaction.

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About Thermochemistry and Energetics of Chemical Reactions

Thermochemistry measures energy changes in chemical reactions and distinguishes exothermic from endothermic processes. Work covers systems, surroundings and state functions, internal energy, the first law of thermodynamics, enthalpy and Hess's law, including the sign conventions used when heat enters or leaves a system.

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