Consider the following spontaneous reactionNi2+ + Mn→ Ni + Mn2+.If a voltaic cell is made based on this reaction then conventional representation of the cell will be
Correct answer: B. Mn , Mn2+ ║ Ni2+ , Ni
- A. Ni , Ni2+ ║ Mn2+ , Mn
- B. Mn , Mn2+ ║ Ni2+ , Ni
- C. Mn2+ , Ni ║ Ni , Ni2+
- D. Ni , Ni ║ Mn , Mn2+
Explanation
In a voltaic cell, the half-reaction with the higher standard reduction potential (E) acts as the cathode (where reduction occurs), and the half-reaction with the lower standard reduction potential acts as the anode (where oxidation occurs). The electrons flow from the anode to the cathode in an external circuit.The given spontaneous reaction is:Ni2+MnNi + Mn2+Breaking it into half-reactions:1. Ni2+ +2e- Ni2. Mn Mn2+ +2eLooking at the standard reduction potentials, we see that the reduction potential for the half- reaction involving Ni is greater than that of Mn. Therefore, Ni will act as the cathode and Mn as the anode.The conventional representation of the cell will be written with the anode on the left and the cathode on the right .so correct answer is b.Mn , Mn2+ ║ Ni2+ , Ni
Last updated
About Electrochemistry
Electrochemistry describes electron transfer through oxidation and reduction, identifies oxidizing and reducing agents, and applies oxidation numbers to balance redox equations. It also covers electrode potential and the standard hydrogen electrode, which provides the reference for comparing the reduction tendencies of other electrodes.
Practise Electrochemistry
696 free Electrochemistry MCQs from Chemistry, each with the correct answer and an explanation. Unlimited attempts, no account needed.
Exams that ask Chemistry questions like this
Chemistry is on 12 papers prepared for on TestUstad, and all of them draw the same bank, so this question is worth knowing for every one of them.
Related questions
10-2 mole of Fe3O4 is treated with excess KI solution in presence of dilute H2SO4, the products are Fe2+ and I2(g). What volume of 0.1 (M) Na2S2O3 will be needed to reduce the liberated I2(g)?
+3 and +5 oxidation states are often shown by:
3 faraday of electricity is passed through molten Al2O3 , aqueous solution of CuSO4 and molten NaCl taken in three different electrolytic cells. The amount of Al, Cu and Na deposited at the cathodes will be in the ratio of:
5.3 gm of M2CO3 is dissolved in 150 ml of 1N HCl. The unused acid required 100 ml of 0.5N NaOH. Hence equivalent weight of M is:
8H++ MnO4- → Mn2+ + 4H2O , which one is correct about given equation?