Moderate

The vapor pressure of water at room temperature is 23.8 mm Hg. The vapour pressure of an aqueous solution of sucrose with mole fraction 0.2 is equal to:

Correct answer: A. 19.04 mm Hg

  • A. 19.04 mm Hg
  • B. 24.2 mm of Hg
  • C. 21.42 mm of Hg
  • D. 21.4 mm of Hg

Explanation

The vapor pressure of a solution can be calculated using Raoult's law which states that the vapor pressure of a solution is directly proportional to the mole fraction of the solvent in the solution. Mathematically, it can be expressed as:P = X_solvent x P°_solventwhere P is the vapor pressure of the solution, X_solvent is the mole fraction of the solvent, and P°_solvent is the vapor pressure of the pure solvent.In this case, the solvent is water, and the mole fraction of sucrose is 0.2. Therefore, the mole fraction of water is:X_water = 1 - X_sucrose = 1 - 0.2 = 0.8The vapor pressure of pure water at room temperature is 23.8 mm Hg. Substituting these values in Raoult's law:P = X_water x P°_water = 0.8 * 23.8 = 19.04 mm HgTherefore, the vapor pressure of the aqueous solution of sucrose with mole fraction 0.2 is 19.04 mm Hg. Option A is the correct answer.

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Mole calculations connect mass, number of particles and Avogadro's number, while balanced equations provide the mole ratios used in stoichiometry. Questions cover limiting and excess reactants, theoretical yield and percentage yield, including identifying which reactant is consumed first and comparing the actual product with the maximum possible product.

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